Oxygen Difluoride or OF2 is a chemical compound created by the reaction in between halogen fluorine and also dilute aqueous equipment of NaOH ( sodium hydroxide ).

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The equation for the preparation of Oxygen Difluoride:

2F2 + 2NaOH ——> OF2 + 2NaF + H2O

It is a colorless gaseous link exhibiting a solid peculiar odor and acts together an oxidizer. It has actually a boiling allude of 128.40 K and a melting point of 49.3 K. It has actually a molar massive of 53.996 g/mol and a density of 1.88 g/l together a gas at room temperature.

Although it has its usage as a solid oxidizing agent, because that example, in propellants of rocket fuels, this property likewise makes the compound unsafe.

OF2 have the right to explode on call with water and also is claimed to be extremely corrosive to the skin. It can also affect the eyes and the cardiovascular system.

Let us have a quick yet detailed look into the inside of the molecule and discuss that is nature of chemical bonding.

OF2 Lewis Structure

Do you know that several factors make atom come together and also combine to kind several different chemical compounds?

When atom come together and also create bonds, a new molecule is created.

Usually, the electrons in the outermost shell of one atom, also known together valence electrons, take component in chemistry bonding.

Lewis Structure, thus, is a basic and constructive procedure to sketch a diagrammatic depiction of a molecule through the help of electron-dot structures.

It provides us a 2D figure and helps us have actually a short idea around the electron arrangement and also the type of bond development without walk much into detail.

Now, we will comment on the actions to form the Lewis structure of OF2.

Steps to form OF2 Lewis structure Diagram

Step 1: Find the Total variety of Valence Electrons.

The very first and foremost action is to calculation the total variety of valence electrons in an OF2 molecule.

Oxygen belonging to group 16, the chalcogen family, and also has a valency that 6. Fluorine belongs to the family of halogen in group 17 and has a valency the 7.

Therefore, the total number of valence electron = 6 + 7*2 = 20.

Step 2: Identify the main Atom

Now, we need to decipher the central atom in this molecule. If we look in ~ the Pauling Electronegativity chart, us can uncover out the the the very least electronegative element among oxygen and also fluorine is Oxygen (O).


The central atom in one oxygen difluoride molecule is Oxygen.

Step 3: Sketch the skeleton Diagram that the Molecule

In Lewis Structure, we use atomic symbols favor C because that carbon, H for hydrogen to represent the ingredient atoms, and electron dot notation to stand for the valence covering electrons.

Let united state look in ~ the below skeletal sketch:

The atom symbols:


Atomic symbols in addition to dot notations:


Step 4: Octet rule 

The key group facets ( group 1 to team 17 ) the the regular table have actually a tendency to attain the octet configuration of the noble gas facets present in group 18 the the same period. This is recognized as octet fulfillment because the aspects want to attain eight electrons in their valence shells.

For example, Carbon has tendency to acquire a Neon configuration.

Exception: Hydrogen has tendency to achieve Helium configuration, thus only 2 electrons in the outer shell.

Here, if we look in ~ the octet rule, both the fluorine atoms have accomplished a valency the eight. The exact same goes because that the main oxygen atom.

Step 5: Formal charge Concept

Before we continue to confirm any sketch to be the perfect Lewis framework for a provided molecule or ionic structure, we require to examine the formal charge values.


For Oxygen: Formal charge = 6 – 0.5*4 – 4 = 6 – 2 – 4 = 0.

For every Fluorine atom: Formal charge = 7 – 0.5*2 – 6 = 7 – 1 -6 = 0.

Since the aspects are current in their least feasible formal fee values, us have accomplished our perfect Lewis structure configuration.

Let united state see:


Here, oxygen develops a single bond through each that the fluorine atoms (O-F).

OF2 molecule Geometry

We have already found the 2D Lewis framework diagram of the Oxygen Difluoride molecule.

Now, we space going come decipher the 3D molecular shape. Via Lewis Structure, we have actually realized the form of shortcut formed and the number of lone or unbonded pairs of valence electrons present in an OF2 molecule.

Our next step is to usage Valence shell Electron Pair Repulsion concept (VSEPR) to find the exact molecular geometry in addition to the link angles.

Like fee electrons develop a negatively fee cloud surrounding the atom nuclei and repulsion is created. The VSEPR design tends to minimize or minimize the repulsive forces and balance the stability of any type of given molecule, in this case, OF2.

Let us look at this VSEPR chart mirroring AXN notations:


According to AXnEx notation the VSEPR theory,

A: central atom ( Oxygen )

X: no. Of bordering atoms, ‘n’ = 2 ( Fluorine )

E: no. The lone bag of electron of the main atom, ‘X = 2.

The VSEPR notation because that the OF2 molecule is AX2E2. According to the over chart, we have actually a bending molecule structure.

The bond angle is around 103 degrees (due come the repulsion the the lone pair).



In chemistry, an orbit is a addressed path approximately the cell nucleus in i beg your pardon electrons often tend to move or revolve. An orbital, ~ above the various other hand, is defined to it is in the probability that the existence of one electron in any given local space.

Atomic orbitals space of number of shapes choose spherical, dumb-bell, clover-leaf, or doughnut to name a couple of of the complicated varieties. We have actually s,p,d,f atomic orbitals ( AOs ).

Electrons have the right to be explained via your wave attributes in quantum mechanics. If we take into account the mix of wave functions of numerous atomic orbitals, we come throughout the procedure of hybridization.

For example, the wave attributes of the s and a 2px orbitals offer rise come sp hybridization i beg your pardon usually results in a direct geometry.

Hybridization in OF2

Let united state look in ~ the electronic configuration that oxygen and fluorine in your ground states.

O: 1s2 2s2 2p4

F: 1s2 2s2 2p5


After forming bonds through halogen F and also attaining octet configuration, the electronic structure that O looks prefer this:


We, therefore, have actually in the outermost covering of the central oxygen atom, 4 hybridized orbitals: 2s, 2px, 2py, 2pz.

Steric number = number of atoms bonded to main atom inside a molecule + number of lone pair of electron attached to the central atom

Also, steric number = 2 + 2 = 4.

Therefore, we have actually sp3 hybridization because that the main oxygen atom in a molecule of oxygen difluoride ( OF2 ).

OF2 Polarity

Let us know at very first what we typical by the very famous and common terminology: Polarity.

Polarity can be identified as the physical building of any type of molecule or chemical compound where the ingredient atomic facets can own either optimistic or an adverse charges or both.

We have already seen the Pauling Electronegativity chart. Each and every element of the main teams in the periodic table has a details value of electronegativity.

When atoms of the same aspect come with each other in equal ratio, the charge worths neutralize themselves and also the net dipole is zero, because of this the molecule is non-polar. Direct or symmetrical chemistry molecules space usually non-polar. ( e.g. : H2 )

However, if molecules consist the uneven partial charge distributions because of a distinction in electronegativity or the molecular shape is asymmetrical, the net dipole no cancel or becomes zero and also we have actually a polar molecule.( e.g. : H3PO4, HCl ).

You can additionally refer come the polarity the HCl.

Is OF2 a polar molecule?

Let us have a quick look right into the molecular form of Oxygen Difluoride. That is almost comparable to H2O and in both cases, the central O has actually two lone bag on the top.

The electronegativity worth of Oxygen is 3.44. And, the of fluorine is 3.98.

Since oxygen is an ext electropositive than fluorine atoms, it will certainly possess a partial hopeful charge ( δ+ ) and also each the the F atoms will certainly possess a an unfavorable partial fee ( δ- ).

So, we have the right to see the there is one electronegativity difference and henceforth the net dipole moment is not equal to zero.

Again, OF2 is not a symmetrical direct structure. The lone bag on the central Oxygen atom give it a bent molecule geometry which each other the English letter V.

We have actually gone with both the uneven charge distribution and the asymmetry the Oxygen Difluoride.The molecule is polar in nature.

For in-depth information, friend must additionally read out the short article written around the polarity that OF2.

OF2 Molecular orbit (MO) Diagram

Valence Bond concept is essential for explaining chemical bonding within a molecule structure yet it has several limitations or drawbacks.

Here, come the molecule Orbital theory or MOT.

In MOT, us take right into account the ide of molecular orbitals (MOs) which room orbitals the the molecule together a whole and also not just those of constituent individual atoms.

It considers electrons to be delocalized and also results in producing bonding and also anti-bonding interactions in orbitals.

To showcase the relative energy levels of the AOs and also the resultant MOs, we have the Molecular orbital diagrams.

The lower energy molecular orbit is the bonding and also the higher energy is the anti-bonding orbital.

The below-mentioned diagram provides us the separation, personal, instance MO diagrams of Oxygen and also Fluorine separately, the atoms that make up a molecule that OF2.



In this article, us have disputed the form of chemical bonding developing inside one OF2 molecule. Oxygen Difluoride is an interesting molecule that was found accidentally and also later had several applications although it was toxic in nature.

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We have actually covered Lewis Structure, VSEPR theory to determine molecular geometry, Hybridization, Polar nature, and a quick discussion top top MO diagram about oxygen difluoride.